(5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1)
Identifieur interne : 000096 ( France/Analysis ); précédent : 000095; suivant : 000097(5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1)
Auteurs : Anissa Mansour [Tunisie] ; Mohamed Salah Belkhiria [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
The asymmetric unit of the title compound, [Co(C44H28N4)]·C12H24O6, contains one half of a CoII(TPP) (TPP is tetraphenylporphyrin) complex and one half of an 18-crown-6 molecule of crystallization, both lying on inversion centers. The CoII(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 molecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether molecule. An ethylene group of the 18-crown-6 molecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7).
Url:
DOI: 10.1107/S1600536810012080
PubMed: 21579007
PubMed Central: 2979047
Affiliations:
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PMC:2979047Le document en format XML
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xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie de Coordination, CNRS UPR 8241, 205 route de Norbonne, 31077 Toulouse, Cedex 04,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences de Monastir, Avenue de l’environnement, 5019 Monastir,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country 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wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences de Monastir, Avenue de l’environnement, 5019 Monastir,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie de Coordination, CNRS UPR 8241, 205 route de Norbonne, 31077 Toulouse, Cedex 04,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name><affiliation wicri:level="1"><nlm:aff id="a">Département de Chimie, Faculté des Sciences de Monastir, Avenue de l’environnement, 5019 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The Co<sup>II</sup>(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 molecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether molecule. An ethylene group of the 18-crown-6 molecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7).</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>France</li><li>Tunisie</li></country></list><tree><country name="Tunisie"><noRegion><name sortKey="Mansour, Anissa" sort="Mansour, Anissa" uniqKey="Mansour A" first="Anissa" last="Mansour">Anissa Mansour</name></noRegion><name sortKey="Belkhiria, Mohamed Salah" sort="Belkhiria, Mohamed Salah" uniqKey="Belkhiria M" first="Mohamed Salah" last="Belkhiria">Mohamed Salah Belkhiria</name><name sortKey="Nasri, Habib" sort="Nasri, Habib" uniqKey="Nasri H" first="Habib" last="Nasri">Habib Nasri</name></country><country name="France"><noRegion><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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